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Sam Oliver (Bret Harrison) - The protagonist of the show, Sam is a college dropout and all-around slacker who, thanks to a deal made by his parents before he was born, becomes a bounty hunter for the devil when he turns 21. He has a crush on his coworker Andi, which appears to be more than reciprocated. Upon learning of his infernal debt, Sam initially thought that he was instantly doomed to be dragged down to Hell, only to be informed by the Devil that he is required to function as a bounty hunter for Hell - for the rest of his life. He now collects souls for the Devil using a vessel (which varies episode after episode), with the assistance of his best friends, Sock and Ben. At times Sam is also given various powers to capture each soul, but these are often as much a hindrance as a help. A quitter by nature, his morality was immediately pressed when he realized that if he didn't go along with his part of the bargain, more and more people would be hurt because he failed to capture the escaped souls.
Bert "Sock" Wysocki (Tyler Labine) - The lowest-performing salesman at 'The Work Bench', Sock spends most of his time sleeping in the stock shelves, planning his topless home supply store, and other time-wasting activities. Fortunately, he is apparently braver than his slacker persona suggests, having encouraged (and assisted) Sam into re-capturing the arsonist escaped soul after it injured Ben on the night the trio first decided to capture it (and was rather impatient as he and Sam waited for the Dirt Devil vacuum cleaner vessel to charge up to full power before they can use it against the escaped soul). He assists Sam (his best friend), with collecting souls. He is not above criminal activity in his attempts to improve his life - replacing Josie's belongings using stolen money, using her ID to access the city morgue, stealing from work, and forging Sam's and Ben's signatures on a lease.
The Devil (Ray Wise) - Smooth-talking and debonair, the Devil claims the rights to Sam's soul thanks to a deal he made with Sam's parents before Sam was even born. Although he knows how it all ends ("God wins"), he is determined to do as much as he can to oppose God until the end. He convinces Sam that he (Sam) is doing good by clearing the world of the escaped evil souls. While firm at times, the Devil has never expressed outright anger, in spite of Sam's frequent complaints and meddling (convincing the Devil's girlfriend to break it off, and souring a deal witha musician who would have sold his soul). He has extreme supernatural powers and often teleports an unsuspecting Sam to locations that serve to exemplify whatever subject he wishes to speak with Sam about. He also has a habit of providing Sam "motivation" in catching escaped souls, usually by informing him that someone just died due mainly to Sam's inaction - a habit which generally gets acceptable results. He is nigh-indestructible, as demonstrated when he invited a frustrated Sam to take several swings at him with an aluminium baseball bat; not even flinching as the blows landed without effect. When dealing with humans unaware of his true nature, he uses the pseudonym "Jerry Belvedere," as seen in his dealings with Mimi Hansen and Ryan Milner.
Ben (Rick Gonzalez) - One of Sam and Sock's coworkers and friends, he knows Sam is working for Satan as a bounty hunter and tries to help him out. Has incredible luck with women. Seems to be prone to getting hurt when assisting Sam in capturing an escaped soul. He is generally seen as the brain of the trio as he is very informative towards his colleagues (Sock in particular), and frequently suggests that they make use of any the available gear at the Work Bench whenever they go out Soul-hunting. He initially sought training as a priest and has an extensive knowledge of the Bible, and often raises theological questions about the nature of their missions and the Devil's involvement.
Andi Prendergast (Missy Peregrym) - Sam's attractive coworker and object of his unspoken affections. Something of a tom-boy, she gets along well with her co-workers at the Work-Bench, all besides Ted. After being let down by Sam multiple times, she is slowly realizing something is different about him now, and she is not being told what.

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